2-[(Adamantan-1-yl)aminomethyl]-4-chlorophenol hemihydrate

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2-[(Adamantan-1-yl)amino­meth­yl]-4-chloro­phenol hemihydrate

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Di-μ-chlorido-bis­{bis­[4-(adamantan-1-ylcarbamo­yl)pyridine-κN]chlorido­copper(II)} hemihydrate

In the centrosymmetric dimeric title compound, [Cu(2)Cl(4)(C(16)H(20)N(2)O)(4)]·0.5H(2)O, the Cu(II) atom is in a distorted trigonal-bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamo-yl)pyridine ligands. The amine N atoms are involved in intra-molecular N-H⋯O and inter-molecular N-H⋯Cl hydrogen bonds. The...

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trans-Tetra­kis[N-(adamantan-1-yl)pyridine-4-carboxamide]­dichlorido­manganese(II)–N-(adamantan-1-yl)pyridine-4-carboxamide (1/2)

The asymmetric unit of the title compound, [MnCl(2)(C(16)H(20)N(2)O)(4)]·2C(16)H(20)N(2)O, is composed of two coordinating N-(adamantan-1-yl)pyridine-4-carboxamide mol-ecules, one Cl(-) anion, an Mn(II) ion, lying on an inversion centre, and one free N-(adamantan-1-yl)pyridine-4-carboxamide mol-ecule. The distorted octa-hedral Mn environment comprises two terminal Cl atoms and four monodentate ...

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2-(Adamantan-1-yl)-5-(4-nitro­phen­yl)-1,3,4-oxadiazole

The title mol-ecule, C(18)H(19)N(3)O(3), lies on a mirror plane that bis-ects the adamantyl group. In the crystal, C-H⋯O and C-H⋯N inter-actions lead to supra-molecular chains along [100]. These assemble into layers in the ab plane via π-π inter-actions [centroid-centroid distance = 3.6548 (7) Å] between the oxadiazole and benzene rings.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812045175